Current progress on 3D graphene-based photocatalysts: From synthesis to photocatalytic hydrogen production. (24th February 2021)

• Record Type: Journal Article
• Authors: Mohd Shah, Nur Rabiatul Adawiyah; Mohamad Yunus, Rozan; Rosman, Nurul Nabila; Wong, Wai Yin; Arifin, Khuzaimah; Jeffery Minggu, Lorna
• Is Part Of: International journal of hydrogen energy. Volume 46:Number 14(2021)
• Page Start: 9324
• Page End: 9340
• Publication Date: 2021-02-24
• Subjects: 3D graphene -- Transition metal dichalcogenides -- Metal oxide -- Photocatalysts -- Photocatalytic hydrogen generation; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2020.12.089
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: Hydrogen (H2 ) is considered an alternative energy carrier for future clean energy systems in many applications. The three-dimensional (3D) graphene is one of the promising candidates for various applications especially in photocatalytic H2 production due to its high electron conductivity, mechanical stability, fast electron transfer, and large surface area. Exploring the changes in the physical properties from different dimensionalities can be interesting because a 3D structure may improve the photocatalytic efficiency in terms of enhancing the light adsorption, increasing the accessible active surface, and improving the charge transport. Graphene can act as an electron acceptor and cocatalyst, and combining the graphene with metal oxides, transition metal dichalcogenides, or other semiconducting materials can enhance the photocatalytic activity of composites. Therefore, the synthesis, characterization, mechanism, and performance of the 3D graphene-based photocatalyst in the photocatalytic H2 production are comprehensively discussed. The current progress and future challenges in the H2 generation is also discussed in this review. Graphical abstract: Image 1 Highlights: There are various methods to synthesis 3D graphene-based photocatalyst. 3D graphene-based photocatalytic properties were reviewed. Adding co-catalyst to improve light absorption and reduced charge recombination. Current progress of 3D graphene-based photocatalyst for hydrogen production.