Defect Engineering for Efficient Cu2ZnSnS4 Solar Cells via Moisture‐Assisted Post‐Deposition Annealing. Issue 18 (6th July 2022)

• Record Type: Journal Article
• Authors: Sun, Heng; Huang, Jialiang; Young, Trevor L.; Cong, Jialin; Li, Jianjun; Sun, Kaiwen; Yan, Chang; Soufiani, Arman Mahboubi; Cui, Xin; Nielsen, Michael P.; Zhang, Xueyun; Stride, John A.; Green, Martin A.; Hao, Xiaojing
• Is Part Of: Advanced optical materials. Volume 10:Issue 18(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-07-06
• Subjects: defect engineering -- interdiffusion -- kesterites -- local chemical composition -- moisture‐assisted post‐deposition annealing; Optical materials -- Periodicals; Photonics -- Periodicals; 620.11295
• DOI: 10.1002/adom.202200607
• Languages: English
• ISSNs: 2195-1071

Abstract

Abstract: Sulfide kesterite Cu2 ZnSnS4 (CZTS) solar cells, containing earth‐abundant and environmentally benign constituents, are regarded as promising candidates for thin‐film photovoltaic technologies. CZTS device performance, however, is currently limited by severe nonradiative recombination caused by abundant deep‐level defects. Herein, an effective defect engineering approach for high bandgap CZTS solar cells using a newly introduced moisture‐assisted post‐deposition annealing treatment is reported. This treatment modifies the local chemical composition within the heterojunction and CZTS grain boundaries and enhances the incorporation of Cd within the CZTS layer during CdS deposition. Cd not only accumulates at the grain boundaries, but it also presents in grain interiors where it occupies Cu lattice sites. The overall modification of the local chemical environment suppresses deep level defects and activates relatively shallow acceptor CuZn antisites and Cu vacancies, giving rise to remarkably improved device performance. This work opens a new direction for defect engineering of kesterite materials, which may also be applicable to other thin film semiconductors. Abstract : A new defect engineering route is achieved by an innovative moisture‐assisted post‐deposition annealing (MAPDA) process. The removal of Na due to MAPDA promotes Cd diffusion during the CdS deposition. The variations in distributions of trace elements and the near‐stoichiometric compositions facilitate the suppression of deep‐level defects and the generation of favorable shallow defects.