Amino‐Acid‐Induced Circular Polarized Luminescence in One‐Dimensional Manganese(II) Halide Hybrid. Issue 48 (30th June 2022)

• Record Type: Journal Article
• Authors: Xuan, Hong‐Li; Sang, Yu‐Feng; Xu, Liang‐Jin; Zheng, Da‐Sheng; Shi, Cui‐Mi; Chen, Zhong‐Ning
• Is Part Of: Chemistry. Volume 28:Issue 48(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-06-30
• Subjects: amino acids -- circular dichroism -- circular polarized luminescence -- halide hybrids; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.202201299
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: Circular polarized luminescence (CPL)‐active materials attract great attentions owing to their widely applications in 3D optical displays and encrypted transmission. Inspired by the strategies adopted in perovskite based CPL materials, herein, CPL‐active hybrids (D)‐ and (L)‐(tert‐butyl prolinate)MnCl3 were successfully prepared by assembling chiral D/L tert‐butyl prolinate with manganese (II) chloride. Single crystal structures show the as‐formed hybrids possess one‐dimensional (1D) structure containing linear chains of face‐sharing MnCl6 octahedral surrounded by prolinate cations. The 1D Mn(II) hybrids display strong red emission peaked at 646 nm with PLQY of 67.1 % and 57.2 % for d ‐type and l ‐type, respectively, representing the highest PLQY for 1D Mn II hybrids. Interestingly, the 1D Mn(II) hybrids exhibit prominent circular dichroism (CD) signals and remarkable CPL activity with the dissymmetry factor g of 6.1*10 −3 and −6.3*10 −3 from 550 to 800 nm for (D)‐ and (L)‐( tert ‐butyl prolinate)MnCl3, respectively, owing to the existence of chiral cations. It is worthy noted the obtained g represents the highest value for non‐lead organic–inorganic hybrids. Abstract : Highly emissive 1D manganese(II) halide hybrid is successfully prepared by self‐assembly of accessible amine acid salt and low‐cost manganese chloride. The known d–d transition of Mn 2+ in octahedral coordination results in strong red emission with PLQY as high as 67.1 %. The as‐formed 1D manganese(II) hybrids exhibit excellent CD signals in ground state and distinguished CPL activity with dissymmetry factor g as high as 6.3*10 −3 in excited state due to the existence of chiral amine acid salt.