An NHC-catalyzed [3+2] cyclization of β-disubstituted enals with benzoyl cyanides. Issue 70 (4th August 2022)
- Record Type:
- Journal Article
- Title:
- An NHC-catalyzed [3+2] cyclization of β-disubstituted enals with benzoyl cyanides. Issue 70 (4th August 2022)
- Main Title:
- An NHC-catalyzed [3+2] cyclization of β-disubstituted enals with benzoyl cyanides
- Authors:
- Liu, Wangsheng
Zhang, Linrui
Liao, Xiaoyun
Chen, Jiean
Huang, Yong - Abstract:
- Abstract : The NHC-catalyzed asymmetric [3+2] cyclization of benzoyl cyanides to homoenolate generated in situ from enals was reported. Abstract : The NHC-catalyzed asymmetric [3+2] cyclization of benzoyl cyanides to homoenolate generated in situ from enals was reported. This methodology leads to the efficient construction of a series of chiral cyclic compounds bearing vicinal quaternary stereocenters under mild reaction conditions. Additionally, the representative large-scale and derivatization reactions of the chiral cyclic products reveal the potential synthetic utility of this protocol.
- Is Part Of:
- Chemical communications. Volume 58:Issue 70(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 70(2022)
- Issue Display:
- Volume 58, Issue 70 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 70
- Issue Sort Value:
- 2022-0058-0070-0000
- Page Start:
- 9742
- Page End:
- 9745
- Publication Date:
- 2022-08-04
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc04025e ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 23201.xml