Biomimetic control of charge transfer in MOFs by solvent coordination for boosting photocatalysis. Issue 70 (17th August 2022)

• Record Type: Journal Article
• Authors: Wang, Zejin; Ding, Rui; Zhang, Jie; Chen, Linrong; Wang, Ying; Liu, Jianguo; Zou, Zhigang
• Is Part Of: Chemical communications. Volume 58:Issue 70(2022)
• Page Start: 9830
• Page End: 9833
• Publication Date: 2022-08-17
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc03333j
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Torsion of perylene in Ni-MOFs caused by solvent coordination accelerates electron transmission speed. Abstract : The role of the coordination solvent in MOFs with photocatalysis can't be ignored. Novel [Ni(PTCA)·sol]-MOFs with a 3D open wavy-layered structure are selected for in-depth study by imitating the internal environment of a chameleon. The results confirm that the coordination solvent can modulate the band structure and the polarity is the key to accelerate the formation of intermediate H*.