Isolation of uranium(iii) primary phosphido complexes. Issue 69 (11th August 2022)

• Record Type: Journal Article
• Authors: Perales, Diana; Bhowmick, Rina; Zeller, Matthias; Miro, Pere; Vlaisavljevich, Bess; Bart, Suzanne C.
• Is Part Of: Chemical communications. Volume 58:Issue 69(2022)
• Page Start: 9630
• Page End: 9633
• Publication Date: 2022-08-11
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc02207a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Low-valent uranium(iii ) primary phosphido complexes supported by hydrotris(3, 5-dimethylpyrazolyl)borate (Tp*) were synthesized with phosphines of varying steric and electronic profiles. Abstract : Low-valent uranium(iii ) primary phosphido complexes supported by hydrotris(3, 5-dimethylpyrazolyl)borate (Tp*) were synthesized with phosphines of varying steric and electronic profiles. Compounds were characterized by multinuclear NMR spectroscopy ( 1 H, 11 B, 31 P NMR), infrared spectroscopy, electronic absorption spectroscopy, X-ray crystallography, and quantum chemical calculations.