Augmenting metallobasicity to modulate gold hydrogen bonding. Issue 69 (9th August 2022)
- Record Type:
- Journal Article
- Title:
- Augmenting metallobasicity to modulate gold hydrogen bonding. Issue 69 (9th August 2022)
- Main Title:
- Augmenting metallobasicity to modulate gold hydrogen bonding
- Authors:
- Maltz, Logan T.
Wilkins, Lewis C.
Gabbaï, François P. - Abstract:
- Abstract : Enhancing gold's metallobasicity through chloride to phenyl ligand substitution afforded an observable increase in the strength of the Au(i )⋯H–O hydrogen bond. Abstract : We report the synthesis and characterization of two phosphine gold carbinol species designed to support intramolecular Au⋯H–O hydrogen bonding. Increasing the metallobasicity of gold through chloride to phenyl ligand substitution produced an observable increase in this hydrogen bond's strength which was analyzed experimentally and computationally.
- Is Part Of:
- Chemical communications. Volume 58:Issue 69(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 69(2022)
- Issue Display:
- Volume 58, Issue 69 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 69
- Issue Sort Value:
- 2022-0058-0069-0000
- Page Start:
- 9650
- Page End:
- 9653
- Publication Date:
- 2022-08-09
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc03328c ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 23198.xml