Barrier permeation properties of EVOH thin-film membranes under aqueous and non-aqueous conditions. Issue 4 (August 2018)

• Record Type: Journal Article
• Authors: McWatters, Rebecca S.; Rowe, R. Kerry
• Is Part Of: Geotextiles and geomembranes. Volume 46:Issue 4(2018:Aug.)
• Page Start: 529
• Page End: 541
• Publication Date: 2018-08
• Subjects: Ethylene vinyl alcohol -- Geomembranes -- Vapour barriers -- Diffusion -- Relative humidity -- Organic contaminants -- Temperature; Membranes (Technology) -- Periodicals; Membranes (Technology); Periodicals; Electronic journals; 624.189
• DOI: 10.1016/j.geotexmem.2018.03.007
• Languages: English
• ISSNs: 0266-1144

Abstract

Abstract: Ethylene vinyl alcohol (EVOH) copolymers can provide a superior barrier to hydrocarbons and are increasingly being used in co-extruded geomembranes for geoenvironmental applications. These thin-films behave differently under different humidity conditions. This study investigated the permeation properties of toluene through two EVOH thin-films (32 mol% ethylene and 44 mol% ethylene) for both non-aqueous and aqueous solutions. The results of this study are used to gain a better understanding of the behaviour of the EVOH layer used in co-extruded geomembranes. The thin-film results are compared with published values for co-extruded linear low density polyethylene (LLDPE) and high density polyethylene (HDPE) geomembranes with an EVOH core. Permeation coefficients are presented over a range of contaminant concentrations from 25 ppm to 99% toluene based on almost five years of continuous testing and the effect of moisture is discussed. A number of EVOH thin-films were affected by humidity (i.e., where moisture diffused into the film) prior to diffusion testing under non-aqueous conditions. This observation led to an investigation of the effect of moisture uptake on the permeation of toluene under non-aqueous testing. In these cases, the 44 mol% thin-film had lower toluene permeation coefficient values than the 32 mol% thin-film. These values were similar to toluene permeation coefficient values from tests with aqueous solutions. When relative humidity was less than 60%, the 32 mol% had slightly lower permeability values than 44 mol% thin-film. However, even when affected by humidity, the permeability of both thin-films were considerably (two to three orders of magnitude) lower than previously observed in a water-saturated solution. Permeation of toluene from a 1/1 toluene/hexane solution was also examined for the 32 mol% EVOH thin-film at temperatures of 23–50 °C and results fit well with a conventional Arrhenius relationship of increasing P g values with increasing temperature.