Self-healing, recoverable epoxy elastomers and their composites with desirable thermal conductivities by incorporating BN fillers via in-situ polymerization. (18th August 2018)

• Record Type: Journal Article
• Authors: Yang, Xutong; Guo, Yongqiang; Luo, Xian; Zheng, Nan; Ma, Tengbo; Tan, Jiaojun; Li, Chunmei; Zhang, Qiuyu; Gu, Junwei
• Is Part Of: Composites science and technology. Volume 164(2018)
• Page Start: 59
• Page End: 64
• Publication Date: 2018-08-18
• Subjects: A. Polymer-matrix composites (PMCs) -- B. Thermal properties -- C. Mechanical testing -- D. Compression molding; Composite materials -- Periodicals; Composite materials; Fibrous composites; Periodicals; 620.118
• DOI: 10.1016/j.compscitech.2018.05.038
• Languages: English
• ISSNs: 0266-3538

Abstract

Abstract: Thiol-epoxy elastomers were firstly prepared by thiol-epoxide nucleophilic ring-opening reaction, and the micron boron nitride ( m BN) fillers were then introduced into the above system via in-situ polymerization, finally to prepare the highly thermally conductive, self-healing and recoverable m BN/thiol-epoxy elastomer composites by hot-pressing method. Results revealed that the thiol-epoxide reaction was highly efficient and stable. The obtained m BN/thiol-epoxy elastomer composite with 60 wt% m BN fillers presented the optimal thermal conductivity ( λ of 1.058 W/mK), excellent self-healing effect & efficiency which is achieved via transesterification reaction (Tensile strength after self-healing could maintain at more than 85% compared to that of original composites), wonderful recoverable performance (Tensile strength after post forming could maintain over 70% compared to that of original composites) and good thermal stability ( T heat-resistance index, T HRI of 149.9 °C). And the improvement in λ value of the m BN/thiol-epoxy elastomer composites was beneficial to the promotion of the self-healing systems relying on thermal response.