Comb-assisted cavity ring down spectroscopy of 17O enriched water between 7443 and 7921 cm−1. (December 2017) - Mondelain, D.
Abstract: The room temperature absorption spectrum of water vapor highly enriched in 17 O has been recorded by Cavity Ring Down Spectroscopy (CRDS) between 7443 and 7921 cm −1 . Three series of recordings were performed with pressure values around 0.1, 1 and 10 Torr. The frequency calibration of the present spectra benefited of the combination of the CRDS spectrometer to a self-referenced frequency comb. The resulting CRD spectrometer combines excellent frequency accuracy over a broad spectral region with a high sensitivity (Noise Equivalent Absorption, α min ∼ 10 –11 –10 −10 cm −1 ). The investigated spectral region corresponds to the high energy range of the first hexade. The assignments were performed using known experimental energy levels as well as calculated line lists based on the results of Partridge and Schwenke. Overall about 4150 lines were measured and assigned to 4670 transitions of six water isotopologues (H2 16 O, H2 17 O, H2 18 O, HD 16 O, HD 17 O and HD 18 O). Their intensities span six orders of magnitude from 10 –28 to 10 –22 cm/molecule. Most of the new results concern the H2 17 O and HD 17 O isotopologues for which about 1600 and 400 transitions were assigned leading to the determination of 329 and 207 new energy levels, respectively. For comparison only about 300 and four transitions of H2 17 O and HD 17 O were previously known in the region, respectively. By comparison to highly accurate H2 16 O line positions available in the literature, the average accuracy on our line centers is checked to be on the order of 3 MHz (10 −4 cm −1 ) or better for not weak well isolated lines. This small uncertainty represents a significant improvement of the line center determination of many H2 16 O lines included in the experimental list provided as Supplementary Material . Graphical abstract: fx1 Highlights: The CRDS spectrum of 17 O enriched water vapour is recorded between 7443 and 7921 cm -1 . The frequency calibration relies on a self-referenced frequency comb. 1596 H2 17 O transitions were assigned and 329 new energy levels were derived. 404 HD 17 O transitions were assigned and 207 new energy levels were derived. The uncertainty on the center of unblended lines is at most 3 MHz (10 −4 cm −1 ).