Long term stability of electrocaloric response in barium zirconate titanate. Issue 2 (February 2018)

• Record Type: Journal Article
• Authors: Weyland, Florian; Eisele, Thorsten; Steiner, Sebastian; Frömling, Till; Rossetti, George A.; Rödel, Jürgen; Novak, Nikola
• Is Part Of: Journal of the European Ceramic Society. Volume 38:Issue 2(2018)
• Page Start: 551
• Page End: 556
• Publication Date: 2018-02
• Subjects: Electrocaloric effect -- Ferroelectric -- Resistance degradation -- Fatigue -- Lead-free; Ceramic materials -- Periodicals; Composite materials -- Periodicals; Matériaux céramiques -- Périodiques; Composites -- Périodiques; Ceramic materials; Composite materials; Periodicals; Electronic journals; 666.05
• DOI: 10.1016/j.jeurceramsoc.2017.09.018
• Languages: English
• ISSNs: 0955-2219

Abstract

Abstract: The stability of the electrocaloric effect under electric field cycling is an important consideration in the development of solid-state cooling devices. Here we report measurements carried out on Ba(Zr0.2 Ti0.8 )O3 ceramics which reveal that the adiabatic temperature change, polarization-electric field hysteresis loops and dielectric permittivity/loss show stable behavior up to 10 5 cycles. We further demonstrate that the loss in electrocaloric response observed after 10 5 cycles is associated with the migration of oxygen vacancies. As a result, the electrical properties of the material are changed leading to an increase in leakage current and Joule heating. Reversing the polarity of the electric field after every 10 5 cycles changes the migration direction of oxygen vacancies, thereby preventing charge accumulation at grain boundaries and electrodes. By doing so, the electrocaloric stability is improved and the adiabatic temperature remains constant even after 10 6 cycles, much higher than achieved in commercially available barium titanate ceramics.