The role of sulphur in the sulfurization of CZTS layer prepared by DC magnetron sputtering from a single quaternary ceramic target. Issue 10 (July 2018)

• Record Type: Journal Article
• Authors: Jiang, Jinchun; Zhang, Linquan; Wang, Wei; Hong, Ruijiang
• Is Part Of: Ceramics international. Volume 44:Issue 10(2018)
• Page Start: 11597
• Page End: 11602
• Publication Date: 2018-07
• Subjects: CZTS -- Sulfurization -- Decomposition -- Bandgap; Ceramics -- Periodicals; Céramique industrielle -- Périodiques; Ceramics; Periodicals; Electronic journals; 666
• DOI: 10.1016/j.ceramint.2018.03.225
• Languages: English
• ISSNs: 0272-8842

Abstract

Abstract: The influence of sulphur vapour pressure, controlled by its mass, on the grain growth and optoelectronic properties of Cu2 ZnSnS4 (CZTS) films prepared by a two-step procedure based on sputtering was studied. It was found that both the crystallinity and grain size of the films were promoted with the increase of the sulphur vapour pressure, indicating that the crystal growth was controlled by the sulphur vapour pressure. In addition, the crystal growth process of CZTS was investigated by analysing the microstructure and elemental composition of the sulfurized films with different masses of sulphur. It was also found that the content of Sn in the sulfurized films decreased after high-temperature annealing. However, the second phase SnS2 was observed on the sample surface, which led to the increase of the optical band gap of the film. Moreover, we proposed the regulatory mechanism of sulphur vapour pressure in the grain growth of CZTS film. Finally, a highly crystalline p-type kieserite Cu2 ZnSnS4 film with carrier concentration of 8.16 × 10 17 cm −3, mobility of 1.24 cm 2 /V s and optical bandgap of 1.54 eV was obtained. This CZTS layers are expected to fabricate high efficiency thin film solar cells.