A composition design rule for crystal growth of centimeter scale by normal sintering process in modified potassium sodium niobate ceramics. Issue 4 (April 2018)

• Record Type: Journal Article
• Authors: Rahman, Attaur; Cho, Kyung-Hoon; Ahn, Cheol-Woo; Ryu, Jungho; Choi, Jong-Jin; Kim, Jong-Woo; Yoon, Woon-Ha; Choi, Joon-Hwan; Park, Dong-Soo; Hahn, Byung-Dong
• Is Part Of: Journal of the European Ceramic Society. Volume 38:Issue 4(2018)
• Page Start: 1416
• Page End: 1420
• Publication Date: 2018-04
• Subjects: Single crystal -- Pb-free ceramic -- Piezoelectric material -- Composition design; Ceramic materials -- Periodicals; Composite materials -- Periodicals; Matériaux céramiques -- Périodiques; Composites -- Périodiques; Ceramic materials; Composite materials; Periodicals; Electronic journals; 666.05
• DOI: 10.1016/j.jeurceramsoc.2017.11.028
• Languages: English
• ISSNs: 0955-2219

Abstract

Abstract: It has been reported that single crystals could be grown by normal sintering process, without the addition of a seed, in (K, Na)NbO3 (KNN)-based ceramics. The growth of huge grains (approximately 5–30 mm) is due to the donor effect on abnormal grain growth (AGG) in KNN-based ceramics. In this study, a composition design rule is suggested to obtain the large single crystal without the seed addition in KNN-based ceramics. In addition, it is also identified by the microstructure observation that the huge grains can be due to the donor effect on the abnormal grain growth which is found in perovskite materials. The donor ratio must be designed to be located at the range between 0.7% and 0.9% compared to that of Na + ions, in order to obtain the large single crystals in KNN-based ceramics. This range of the donor ratio is narrower than that in BaTiO3 (or SrTiO3 ) ceramics.