Controllable Friction of Green Ionic Liquids via Environmental Humidity. Issue 5 (9th February 2020)

• Record Type: Journal Article
• Authors: Hua, Jing; Björling, Marcus; Larsson, Roland; Shi, Yijun
• Is Part Of: Advanced engineering materials. Volume 22:Issue 5(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-02-09
• Subjects: friction control -- humidity -- ionic liquids -- viscosity; Materials -- Periodicals; 620.11
• DOI: 10.1002/adem.201901253
• Languages: English
• ISSNs: 1438-1656

Abstract

Abstract : Intelligent control of friction is an attractive but challenging topic. In this work, it is investigated if it would be possible to adjust friction in a lubricated contact by controlling environmental humidity. By exploiting the ability to adjust the environmental humidity by various saturated salt solutions, friction behavior of contacts lubricated with Choline l ‐Proline ([Cho][Pro]) is modulated in a wide range of relative humidity (RH). The friction increases when the environmental humidity is increased and decreases when water is partially evaporated to a lower RH. It is thus possible to control friction by environmental humidity. The addition of water in ionic liquids (ILs) causes a decrease in viscosity, but as the tests are calculated to be performed in boundary lubrication the viscosity change is not the main factor for the change in friction. The friction sensitivity of RH can be explained by the effect of adhesion on the water uptake from humid air by [Cho][Pro]. Furthermore, the reversible changes of H‐bond types determined by the water content could be another explanation to the altered friction. Abstract : Friction control through environmental humidity is achieved by using hygroscopic ionic liquids as lubricants. The viscosity of a lubricant decreases with the addition of water. Based on film thickness calculation, friction tests are performed in boundary lubrication; thus the adhesion effect may play an important role in altering the friction.