Oppositely Charged Ti3C2Tx MXene Membranes with 2D Nanofluidic Channels for Osmotic Energy Harvesting. Issue 22 (18th February 2020)

• Record Type: Journal Article
• Authors: Ding, Li; Xiao, Dan; Lu, Zong; Deng, Junjie; Wei, Yanying; Caro, Jürgen; Wang, Haihui
• Is Part Of: Angewandte Chemie international edition. Volume 59:Issue 22(2020)
• Page Start: 8720
• Page End: 8726
• Publication Date: 2020-02-18
• Subjects: membranes -- ion transport -- MXene -- nanofluidics -- osmotic energy (blue energy); Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201915993
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Membrane‐based reverse electrodialysis (RED) is considered as the most promising technique to harvest osmotic energy. However, the traditional membranes are limited by high internal resistance and low efficiency, resulting in undesirable power densities. Herein, we report the combination of oppositely charged Ti3 C2 T x MXene membranes (MXMs) with confined 2D nanofluidic channels as high‐performance osmotic power generators. The negatively or positively charged 2D MXene nanochannels exhibit typical surface‐charge‐governed ion transport and show excellent cation or anion selectivity. By mixing the artificial sea water (0.5 m NaCl) and river water (0.01 m NaCl), we obtain a maximum power density of ca. 4.6 Wm −2, higher than most of the state‐of‐the‐art membrane‐based osmotic power generators, and very close to the commercialization benchmark (5 Wm −2 ). Through connecting ten tandem MXM‐RED stacks, the output voltage can reach up 1.66 V, which can directly power the electronic devices. Abstract : Into the blue : Osmotic energy, known as "blue energy", is derived by capturing this salinity gradient energy between sea water and fresh water. Negatively and positively charged lamellar MXene membranes with confined 2D nanofluidic channels give high‐efficient osmotic energy harvesting, with a high output power density of 4.6 W m −2 by mixing artificial sea water (SW) and river water (RW), which is close to the commercialization benchmark (5 W m −2 ).