Synthesis of tungsten carbide from bimodal tungsten powder produced by electrical explosion of wire. (February 2022)

• Record Type: Journal Article
• Authors: Pervikov, A.V.; Krinitcyn, M.G.; Glazkova, E.A.; Rodkevich, N.G.; Lerner, M.I.
• Is Part Of: International journal of refractory metals & hard materials. Volume 103(2022)
• Publication Date: 2022-02
• Subjects: Tungsten -- Carburization -- Tungsten carbide -- Electrical explosion of wire -- Nanopowders; Heat resistant alloys -- Periodicals; Refractory materials -- Periodicals; Metallography -- Periodicals; Alliages réfractaires -- Périodiques; Matériaux réfractaires -- Périodiques; Métallographie -- Périodiques; Heat resistant alloys; Metallography; Refractory materials; Periodicals; Electronic journals; 669.73
• DOI: 10.1016/j.ijrmhm.2021.105733
• Languages: English
• ISSNs: 0263-4368

Abstract

Abstract: In the present study, bimodal tungsten carbide WC powders are successfully prepared by a two-stage process: electrical explosion of wire (EEW) synthesis of bimodal tungsten powder followed by a carburization reaction. The conditions of the EEW synthesis have been determined, resulting in the preparation of the bimodal powder. During the carburization process, the tungsten carbide WC is formed through the transition phase W2 C. The carbon content in the obtained WC powders is very close to the theoretical value. Also, it was found that a high C/W molar ratio at the carburization stage does not affect the carburization process significantly. Optimal conditions for the tungsten carbide WC synthesis have been determined: calcination at 1200 °C with 8 h dwell and C/W molar ratio to be 1.4. The yield of tungsten carbide is 99 wt% under these conditions. Thus, the carburization process of bimodal tungsten powder may provide a low-cost and high-efficiency route to prepare the WC powders for various applications. Highlights: The use of electrical explosion of wire for the synthesis of bimodal tungsten powder. Synthesis of bimodal tungsten carbide WC powder achieved at 1200 °C. The carburization temperature has a significant effect on the WC synthesis route. Carbon content of final product is very close to the theoretical value of tungsten carbide.