Optimizing critical metals recovery and correlative decontamination from MSWI fly ash: Evaluation of an integrating two-step leaching hydrometallurgical process. (25th September 2022)

• Record Type: Journal Article
• Authors: Tang, Jinfeng; Dong, Shaobin; Feng, Qian; Su, Minhua; Wei, Yongjun; Liang, Jiawei; Zhang, Hongguo; Huang, Lei; Kong, Lingjun; Wang, Nana; Xiao, Enzong; Liu, Yingkui; Tang, Xuan; Xiao, Tangfu
• Is Part Of: Journal of cleaner production. Volume 368(2022)
• Publication Date: 2022-09-25
• Subjects: Factory and trade waste -- Management -- Periodicals; Manufactures -- Environmental aspects -- Periodicals; Déchets industriels -- Gestion -- Périodiques; Usines -- Aspect de l'environnement -- Périodiques; 628.5
• DOI: 10.1016/j.jclepro.2022.133017
• Languages: English
• ISSNs: 0959-6526

Abstract

Abstract: While municipal solid waste incineration (MSWI) fly ash is classified as hazardous waste, it can also serve as an urban mining source for numerous precious metals. Of particular interest are antimony (Sb) and zinc (Zn); the former of which is a strategic and critical metal that is being rapidly depleted, putting society at high risk for supply shortages. In this work, a two-step leaching method for recovering Sb and Zn from MSWI fly ash is proposed. Furthermore, the leaching behavior and adsorption mechanism of Sb in the MSWI fly ash waste stream were also investigated. Results from the first constant pH leaching tests (CPLT) showed that under diluted acidic condition, the maximum amount of Sb released from fly ash was ∼20%. In addition, at pH 4.0, 67% of the fly ash was dissolved, while 79.3% and 12.1% of the Zn and Sb, respectively, were recovered. After optimizing and executing a second Sb leaching procedure (6 M HCl solution at 60 °C), >80% of the Sb was recovered. Thus, the proposed two-step leaching process, consisting of extraction followed by decontamination using a magnetic HAP@CoFe2 O4 adsorbent, can eliminate the Sb in fly ash effluent with a removal efficiency >95%. Moreover, this process produces less toxic products and lowers the effluent residue concentration. As such, the two-step process described herein is suggested for Sb and Zn recovery from fly ash; as it not only enables precious metal recovery, but also aids in treating secondary waste streams produced from urban mining. Graphical abstract: Image 1 Highlights: An integrated method for fly ash and secondary waste treatment was proposed. Both Zn and Sb have great separation factors by pH-dependent leaching at pH 4. >80% of Sb in residue was leached out using 6 M HCl at 60 °C. Heavy metals in effluent were fast and effectively removed by HAP@CoFe2 O4. Treated residue and effluent as by-products were more stable and less toxic.