Novel enantioselective fluorescent sensors for tartrate anion based on acridinezswsxa. (17th May 2017)

• Record Type: Journal Article
• Authors: Wang, Chaoyu; Wang, Peng; Liu, Xiaoyan; Fu, Jiaxin; Xue, Kun; Xu, Kuoxi
• Is Part Of: Luminescence. Volume 32:Number 7(2017)
• Page Start: 1313
• Page End: 1318
• Publication Date: 2017-05-17
• Subjects: enantioselective recognition -- sensor -- tartrate anion; Luminescence -- Periodicals; Bioluminescence -- Periodicals; Chemiluminescence -- Periodicals; Luminescence -- Periodicals; 535.35
• DOI: 10.1002/bio.3327
• Languages: English
• ISSNs: 1522-7235

Abstract

Abstract: Novel chiral fluorescence sensors L‐1 and D‐1 incorporating N ‐Boc‐protected alanine and acridine moieties were synthesized. The recognition ability of the sensors was studied by fluorescence titration, 1 H NMR spectroscopy and density functional theory (DFT) calculations. The sensors exhibited good enantioselective fluorescent sensing ability toward enantiomers of tartrate anion for the selected carboxylate anions and formed 1: 1 complexes by multiple hydrogen bonding interactions.