Nanostructured Rare Earth Nd3+doped Nickel–Zinc–Bismuth Spinel Ferrites: Structural, Electrical and Dielectric Studies. Issue 19 (1st October 2022)

• Record Type: Journal Article
• Authors: Taneja, Shilpa; Thakur, Preeti; Kumar, Rakesh; Hemalatha, S.; Slimani, Yassine; Ravelo, Blaise; Thakur, Atul
• Is Part Of: Ceramics international. Volume 48:Issue 19(2022)Part A
• Page Start: 27731
• Page End: 27738
• Publication Date: 2022-10-01
• Subjects: Ferrites -- Citrate precursor -- XRD -- Resistivity -- Dielectric -- High-frequency application; Ceramics -- Periodicals; Céramique industrielle -- Périodiques; Ceramics; Periodicals; Electronic journals; 666
• DOI: 10.1016/j.ceramint.2022.06.073
• Languages: English
• ISSNs: 0272-8842

Abstract

Abstract: A series of rare earth neodymium (Nd 3+ ) doped Ni–Zn–Bi nanoferrites of composition Ni0.5 Zn0.5 Bi0.04 Ndx Fe1.96-x O4 (x = 0.002, 0.004, 0.006, 0.008, 0.010) has been synthesized by a citrate precursor technique. Structural, morphological, electrical, and dielectric characterizations have been undertaken. X-ray diffraction pattern confirmed cubic spinel ferrite structure of the prepared nanoferrites with crystallite size in the range of 25–30 nm. From the Hall-Williamson graphs, a tensile strain has been noticed due to an expansion of lattice with an increase in Nd composition. The octahedral and tetrahedral modes of vibrations were confirmed by Fourier Transform Infrared spectroscopy (FTIR) peaks at wavenumber 590 cm −1 and 403 cm −1 . The D.C. resistivity performance of the nanoferrites was found in the range of 10 10 Ω cm calculated from the current-voltage plot. Dielectric studies were undertaken at room temperature in the frequency range from 10 kHz to 10 MHz. The dielectric behaviour of the prepared samples reveals that the real part increases from 4.85 to 13.67 and imaginary values rise from 0.49 to 4.46 at 10 5 Hz. The dielectric loss tangent value decreases from 0.34 to 0.15 with the change in Nd ion concentration. The AC conductivity rises from 2.18 × 10 −6 to 2.39 × 10 −5 S/cm at 10 5 Hz. These lower values of loss tangent in Nd doped Ni–Zn–Bi nanoferrites materials are useful in deflection yoke and high-frequency applications. Graphical abstract: Image 1 Highlights: Average crystallite size was found in the range 25–30 nm. Enormous DC resistivity values in the range 2.89 × 10 9 –1.60 × 10 10 Ω-cm were observed. The real part of dielectric constant was found to be in the range 4.85–13.67. Imaginary part of dielectric constant was found in the range 0.49–4.46. AC conductivity was observed in the range 2.18 × 10 −6 - 2.39 × 10 −5 S/cm at 10 5 Hz frequency.