Amino‐Functionalised Hybrid Ultramicroporous Materials that Enable Single‐Step Ethylene Purification from a Ternary Mixture. (1st April 2021)

• Record Type: Journal Article
• Authors: Mukherjee, Soumya; Kumar, Naveen; Bezrukov, Andrey A.; Tan, Kui; Pham, Tony; Forrest, Katherine A.; Oyekan, Kolade A.; Qazvini, Omid T.; Madden, David G.; Space, Brian; Zaworotko, Michael J.
• Is Part Of: Angewandte Chemie. Volume 133:Number 19(2021)
• Page Start: 10997
• Page End: 11004
• Publication Date: 2021-04-01
• Subjects: coordination networks -- crystal engineering -- ethylene purification -- physisorption -- porous materials; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202100240
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Pyrazine‐linked hybrid ultramicroporous (pore size <7 Å) materials (HUMs) offer benchmark performance for trace carbon capture thanks to strong selectivity for CO2 over small gas molecules, including light hydrocarbons. That the prototypal pyrazine‐linked HUMs are amenable to crystal engineering has enabled second generation HUMs to supersede the performance of the parent HUM, SIFSIX‐3‐Zn, mainly through substitution of the metal and/or the inorganic pillar. Herein, we report that two isostructural aminopyrazine‐linked HUMs, MFSIX‐17‐Ni (17=aminopyrazine; M=Si, Ti), which we had anticipated would offer even stronger affinity for CO2 than their pyrazine analogs, unexpectedly exhibit reduced CO2 affinity but enhanced C2 H2 affinity. MFSIX‐17‐Ni are consequently the first physisorbents that enable single‐step production of polymer‐grade ethylene (>99.95 % for SIFSIX‐17‐Ni ) from a ternary equimolar mixture of ethylene, acetylene and CO2 thanks to coadsorption of the latter two gases. We attribute this performance to the very different binding sites in MFSIX‐17‐Ni versus SIFSIX‐3‐Zn . Abstract : Hybrid ultramicroporous materials in which aminopyrazine ligands substitute pyrazine ligands are the first physisorbents that enable polymer‐grade (>99.95 %) ethylene production from ternary C2‐CO2 gas mixtures under ambient conditions thanks to coadsorption of both C2 H2 and CO2 .