A New Basic Ionic Liquid Supported on Magnetite Nanoparticles: An Efficient Phase-Transfer Catalyst for the Green Synthesis of 2-Amino-3-Cyano-4H-Pyrans. (28th May 2022)

• Record Type: Journal Article
• Authors: Fallah-Mehrjardi, Mehdi; Shirzadi, Mahdieh; Banitaba, Sayed Hossein
• Is Part Of: Polycyclic aromatic compounds. Volume 42:Number 5(2022)
• Page Start: 2198
• Page End: 2209
• Publication Date: 2022-05-28
• Subjects: Green synthesis -- multicomponent reaction -- 2-amino-3-cyano-4H-pyran -- supported ionic liquid -- phase-transfer catalyst; Polycyclic aromatic compounds -- Periodicals; 547
• DOI: 10.1080/10406638.2020.1830131
• Languages: English
• ISSNs: 1040-6638

Abstract

Abstract: An efficient and straightforward procedure has been developed for the synthesis of 2-amino-3-cyano-4 H -pyrans via the one-pot three-component reaction of benzaldehydes, malononitrile and 1, 3-dicarbonyl compounds using a new nanomagnetite-supported organocatalyst (MNP@PEG-ImOH) in aqueous media. The MNPs are fully characterized by various techniques including Fourier transform infrared spectroscopy (FT-IR), field-emission scanning electron microscopy (FESEM), energy-dispersive X-ray (EDAX), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and vibrating sample magnetometry (VSM). The catalyst could readily be separated from the reaction mixture using an external magnet and could be reused in subsequent runs without a notable decrease of activity.