Cover Feature: Metal‐Dependent and Selective Crystallization of CAU‐10 and MIL‐53 Frameworks through Linker Nitration (Chem. Eur. J. 28/2021). Issue 28 (22nd April 2021)

• Record Type: Journal Article
• Authors: Rabe, Timo; Svensson Grape, Erik; Engesser, Tobias A.; Inge, A. Ken; Ströh, Jonas; Kohlmeyer‐Yilmaz, Gitta; Wahiduzzaman, Mohammad; Maurin, Guillaume; Sönnichsen, Frank D.; Stock, Norbert
• Is Part Of: Chemistry. Volume 27:Issue 28(2021)
• Page Start: 7591
• Page End: 7591
• Publication Date: 2021-04-22
• Subjects: aluminium -- framework flexibility -- gallium -- molecular simulations -- water adsorption; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.202101338
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract : Starting from 5‐hydroxyisophthalic acid (not shown), in situ nitration leads to different nitrated linker molecules that selectively react with Ga 3+ or Al 3+ ions to Ga‐MIL‐53 and Al‐CAU‐10 type frameworks, respectively. The pale blue and orange light path represents the crystallization of the respective MOF. More information can be found in the Full Paper by N. Stock et al. (DOI: 10.1002/chem.202100373 ).