Modern Electrochemical Aspects for the Synthesis of Value‐Added Organic Products. Issue 21 (19th April 2018)

• Record Type: Journal Article
• Authors: Möhle, Sabine; Zirbes, Michael; Rodrigo, Eduardo; Gieshoff, Tile; Wiebe, Anton; Waldvogel, Siegfried R.
• Is Part Of: Angewandte Chemie international edition. Volume 57:Issue 21(2018)
• Page Start: 6018
• Page End: 6041
• Publication Date: 2018-04-19
• Subjects: electrolysis -- flow electrochemistry -- organocatalysis -- renewable resources -- synthetic methods; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201712732
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: The use of electricity instead of stoichiometric amounts of oxidizers or reducing agents in synthesis is very appealing for economic and ecological reasons, and represents a major driving force for research efforts in this area. To use electron transfer at the electrode for a successful transformation in organic synthesis, the intermediate radical (cation/anion) has to be stabilized. Its combination with other approaches in organic chemistry or concepts of contemporary synthesis allows the establishment of powerful synthetic methods. The aim in the 21st Century will be to use as little fossil carbon as possible and, for this reason, the use of renewable sources is becoming increasingly important. The direct conversion of renewables, which have previously mainly been incinerated, is of increasing interest. This Review surveys many of the recent seminal important developments which will determine the future of this dynamic emerging field. Abstract : The use of electricity in synthesis instead of stoichiometric amounts of reagents is very attractive from both an economic and an ecological point of view. In combination with other concepts and approaches of organic chemistry, this represents a major driving force for research efforts. This Review summarizes many of the recent developments in this area.