Wavelength‐Selective Photopolymerization of Hybrid Acrylate‐Oxetane Liquid Crystals. Issue 19 (26th March 2021)

• Record Type: Journal Article
• Authors: Hoekstra, Davey C.; van der Lubbe, Bodine P. A. C.; Bus, Tom; Yang, Lanti; Grossiord, Nadia; Debije, Michael G.; Schenning, Albert P. H. J.
• Is Part Of: Angewandte Chemie international edition. Volume 60:Issue 19(2021)
• Page Start: 10935
• Page End: 10941
• Publication Date: 2021-03-26
• Subjects: cholesteric liquid crystals -- in situ characterization -- interpenetrating polymer networks -- phase separation -- photopolymerization; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.202101322
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: We report on the wavelength‐selective photopolymerization of a hybrid acrylate‐oxetane cholesteric liquid crystal monomer mixture. By controlling the sequence and rate of the orthogonal free‐radical and cationic photopolymerization reactions, it is possible to control the degree of phase separation in the resulting liquid crystal interpenetrating networks. We show that this can be used to tune the reflective color of the structurally colored coatings produced. Conversely, the structural color can be used to monitor the degree of phase separation. Our new photopolymerization procedure allows for structuring liquid crystal networks in three dimensions, which has great potential for fabricating liquid crystal polymer materials with programmable functional properties. Abstract : A wavelength‐selective photopolymerization process of a hybrid acrylate‐oxetane cholesteric liquid crystal monomer mixture was developed. Control over the sequence and rate of both polymerizations allows for control over phase separation within the interpenetrating network structure. The structurally colored cholesteric coatings could be used to monitor the phase separation.