In Situ Prepared NRCPFs as Highly Active Photo Platforms for in Situ Bond Formation Between Aryldiazonium Salts and Heteroarenes. (12th June 2022)

• Record Type: Journal Article
• Authors: Singh, Satyam; Yadav, Rajesh Kumar; Kim, Tae Wu; Singh, Chandani; Singh, Pooja; Chaubey, Surabhi; Rose, Baimuratova; Gulzhian, Dzhardimalieva; Khare, Prateek
• Is Part Of: Photochemistry and photobiology. Volume 98:Number 4(2022)
• Page Start: 748
• Page End: 753
• Publication Date: 2022-06-12
• Subjects: Photochemistry -- Periodicals; Light -- Physiological effect -- Periodicals; 541.35
• DOI: 10.1111/php.13639
• Languages: English
• ISSNs: 0031-8655

Abstract

Abstract: Covalent perylene frameworks (CPFs) with melamine linkages have newly received rising interest for a variety of applications because of nitrogen‐rich content and high stability. Herein, we account a new simple strategy to in situ attain nitrogen‐rich covalent perylene frameworks (NRCPFs) as highly active photo platforms for in situ bond formation between aryldiazonium salts and heteroarenes (C–H bond arylation) through the controlled photoredox route. Abstract : C–H bond arylation between aryldiazonium salts and heteroarenes through in situ prepared NRCPFs photocatalyst under solar light irradiation. The NRCPFs photocatalyst has been more efficient due to the nitrogen enrich covalent perylene framework which is utilized for C–H bond arylation. C–H bond arylated products have a wide range of industrial and medicinal applications.