Quinuclidinium-piperidinium based dual hydroxide anion exchange membranes as highly conductive and stable electrolyte materials for alkaline fuel cell applications. (10th September 2022)

• Record Type: Journal Article
• Authors: Patil, Smitha S; V, Madhura; Kammakakam, Irshad; Swamy, MH Halashankar; Patil, K Sadashiva; Lai, Zhiping; Rao H N, Anil
• Is Part Of: Electrochimica acta. Volume 426(2022)
• Publication Date: 2022-09-10
• Subjects: Anion exchange membrane -- Dual hydroxide conductor -- Piperidinium -- Quinuclidinium -- Anion conductivity -- Bicyclic quaternary ammonium; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2022.140826
• Languages: English
• ISSNs: 0013-4686

Abstract

Highlights: A dual hydroxide containing quinuclidinum and piperidinium cations were synthesized. Dual hydroxide PES copolymer membrane exhibited enhanced conductivity and phase-separated morphology. Improved alkaline stability was observed for QP-PES membrane in 2M NaOH at 60 °C for 1000 h maintaining 50% of the conductivity. Tethered dual hydroxide membrane yielded 92.3 mWcm −2 power density at a current density of 200 mA cm −2 . Abstract: Anion-exchange membrane fuel cells (AEMFCs) utilizing quaternary ammonium functionalized poly(arylene ether sulfone)s have been rapidly advanced in the clean energy research arena. However, it is highly desirable to integrate the benefits of quaternary ammonium cations in the polymeric membrane systems to achieve a high-power output together with substantial stabilities that significantly reduce the material costs. Herein, we report the tethering of two different quinuclidinium and piperidinium cations separated by a flexible –(CH2 )4 ˗ spacer as a dual hydroxide conductor in the poly(arylene ether sulfone)s copolymer membrane (QP-PES) for enhancing the structural and physical properties as well as the ionic conductivities. The results proved that the tethering of dual hydroxide conductor in the PES backbone led to show maximum hydroxide conductivity of 88 mS cm −1 at 80 °C while enabling a hydrophilic/hydrophobic micro-phase separation due to the presence of flexible alkyl spacer. We also investigated the properties of a single hydroxide conductor exclusively comprising the quinuclidinium cation (Q-PES) and compared it with that of QP-PES. Interestingly, both the Q-PES and QP-PES membranes displayed superior thermal, mechanical, and dimensional stabilities. Most importantly, the QP-PES membrane demonstrated excellent alkaline stability over the period of 1000 h due to the existence of dual hydroxide conductor together with alkyl spacer units. Furthermore, the maximum power density of a H2 /O2 single cell using QP-PES (92.3 mWcm −2 ) is higher than that of QP-PES (70.0 mWcm −2 ). The results provide a greater perception to design the high performance AEM materials. Abstract : Image, graphical abstract .