Synthesis of Aminobismuthanes via Me3SnCl Elimination. Issue 21 (21st June 2017)

• Record Type: Journal Article
• Authors: Schulz, Axel; Thomas, Max; Villinger, Alexander
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 643:Issue 21(2017)
• Page Start: 1406
• Page End: 1414
• Publication Date: 2017-06-21
• Subjects: Aminobismuthane -- Lithiation -- Stannylated aniline -- Synthesis -- Structure elucidation; Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.201700162
• Languages: English
• ISSNs: 0044-2313

Abstract

Abstract : The synthesis of N ‐trimethylstannylamines of the type R N(SnMe3 )H (stannylated anilines) with the sterically encumbered substituents R such as Ter [terphenyl, 2, 6‐bis(2, 4, 6‐trimethylphenyl)‐phenyl], Ar* [2, 6‐bis(diphenylmethyl)‐4‐methylphenyl], and Mes* (supermesityl, 2, 4, 6‐tri‐ tert ‐butylphenyl) is described. These stannylated anilines were treated with BiCl3 leading to the formation of R N(H)BiCl2 (for R = Ter), ( R NH)3 Bi (for R = Mes*), and R N(BiCl2 )2 (for R = Ar*). The synthesis and structure of the starting material R N(SnMe3 )H and the new aminobismuthanes are reported. Abstract :