Construction of an "environment-friendly" CuBx@PU self-supporting electrode toward efficient seawater electrolysis. Issue 15 (14th July 2022)

• Record Type: Journal Article
• Authors: Zhang, Yiran; Fu, Chengyu; Weng, Shuo; Lv, Haiyang; Li, Peng; Deng, Shengwei; Hao, Weiju
• Is Part Of: Green chemistry. Volume 24:Issue 15(2022)
• Page Start: 5918
• Page End: 5929
• Publication Date: 2022-07-14
• Subjects: Environmental chemistry -- Industrial applications -- Periodicals; Environmental management -- Periodicals; 660
• DOI: 10.1039/d2gc01819e
• Languages: English
• ISSNs: 1463-9262

Abstract

Abstract : A series of high-efficiency CuB x -based bifunctional flexible polyurethane plastic electrodes are fabricated by mild electroless plating for durable electrolysis over 1 A cm −2 in seawater, which also promotes the degradation of polyurethane plastics. Abstract : It is of great significance to realize green development of high-efficiency and economical catalysts modified stably on the "white plastic" surface for grid-scale hydrogen production coupled plastic degradation by alkaline seawater splitting. Herein, needle-like copper–boron (CuB x ) is successfully grown in situ on 3D porous polyurethane plastic (PU) via mild electroless plating to obtain the flexible CuB x @PU bifunctional self-supporting electrodes. Owing to its high intrinsic activity, fast electron transfer capacity and 3D loose porous morphology, overpotentials at 10 mA cm −2 in alkaline simulated seawater during the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) are only η 10 = 70 mV and η 10 = 136 mV. The robust electrode only requires 1.45 V to achieve overall water splitting and can continuously work for over 20 h at 100 mA cm −2 . Meanwhile, a series of CuB x -based ternary catalysts are simply modified on a plastic surface by this universal strategy with excellent catalytic performance. Attractively, the CuB x modification layer accelerates plastic aging and breaking down into small molecules of ammonia-ester after long-term seawater electrolysis at an industrial current density (>1 A cm −2 ). This work proposes a meaningful method for theoretical and practical application of green hydrogen production coupled "white pollutant" degradation.