Correlating Cathode Microstructure with PEFC Performance Using FIB-SEM and TEM. Issue 9 (1st January 2017)

• Record Type: Journal Article
• Authors: Okumura, M.; Noda, Z.; Matsuda, J.; Tachikawa, Y.; Nishihara, M.; Lyth, S. M.; Hayashi, A.; Sasaki, K.
• Is Part Of: Journal of the Electrochemical Society. Volume 164:Issue 9(2017)
• Page Start: F928
• Page End: F934
• Publication Date: 2017-01-01
• Subjects: 3D Tomography -- cathode -- electrocatalyst -- FIB-SEM -- microstructure -- PEFC -- porosity; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0581709jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : The cathode electrocatalyst layers of polymer electrolyte membrane fuel cells (PEFCs) are quantitatively investigated for different ratios of Nafion ionomer. This is achieved using focused-ion-beam coupled scanning electron microscopy (FIB-SEM) to reconstruct the three-dimensional microstructure via tomography. Parameters such as the porosity and pore size distribution were calculated from this data. The distributions of Nafion ionomer, carbon support, and platinum nanoparticles were then further clarified using transmission electron microscopy (TEM). Changes in the PEFC performance (notably the I-V characteristics, the electrochemical surface area, the activation overvoltage, and the concentration overvoltage) are thus correlated to electrode microstructure.