Hybrid Ag2VO2PO4/CFx as a High Capacity and Energy Cathode for Primary Batteries. Issue 12 (1st January 2017)

• Record Type: Journal Article
• Authors: Li, Yue Ru; Bruck, Andrea M.; Brady, Alexander B.; Bock, David; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Marschilok, Amy C.
• Is Part Of: Journal of the Electrochemical Society. Volume 164:Issue 12(2017)
• Page Start: A2457
• Page End: A2467
• Publication Date: 2017-01-01
• Subjects: carbon monofluoride -- lithium battery -- silver vanadium phosphorous oxide; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0991712jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : In this report, we describe the electrochemistry of hybrid dual silver vanadium phosphorus oxide/carbon fluoride (Ag2 VO2 PO4 /CFx ) cathodes with various weight ratios. Through modification of the Ag2 VO2 PO4 /CFx ratio, we can control the gravimetric and volumetric capacity, as well as mitigate the voltage drop during high current pulses. The increase in impedance caused by irreversible LiF formation in CFx was reduced by the silver reduction-displacement during electrochemical discharge of the Ag2 VO2 PO4 . Moreover, the addition of graphite was shown to reduce initial voltage delay. When Ag2 VO2 PO4 dominates the electrode mass (i.e. 75/25 Ag2 VO2 PO4 /CFx ) in the hybrid cathode, pulse testing shows less voltage drop and delay, but at the expense of capacity and energy density. As the amount of CFx in the composite increases (i.e. Ag2 VO2 PO4 /CFx ratio of to 50/50 or 25/75), charge capacity and energy density increases, but at the expense of larger voltage drops and delays early in the discharge process. Thus, controlling the Ag2 VO2 PO4 /CFx ratio can be used to tune the electrochemical properties of the dual cathode, allowing for optimization of capacity and power depending on the application.