Rechargeable Zinc-Ion Battery Based on Choline Chloride-Urea Deep Eutectic Solvent. Issue 6 (1st January 2019)

• Record Type: Journal Article
• Authors: Kao-ian, Wathanyu; Pornprasertsuk, Rojana; Thamyongkit, Patchanita; Maiyalagan, Thandavarayan; Kheawhom, Soorathep
• Is Part Of: Journal of the Electrochemical Society. Volume 166:Issue 6(2019)
• Page Start: A1063
• Page End: A1069
• Publication Date: 2019-01-01
• Subjects: Batteries -- choline choride -- deep eutectic solvent -- zinc-ion battery; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0641906jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : Recently, because of their cost effectiveness, high safety and environmental friendliness, zinc-ion batteries (ZIBs) are receiving enormous attention. Until now, aqueous-based ZIBs have been the focus of attention. However, the issues regarding hydrogen evolution, and zinc electrode passivation as well as dendrite formation limit their practical application. In this work, a biocompatible, stable and low-cost choline chloride/ urea (ChCl/urea) deep eutectic solvent is reported as an alternative electrolyte for rechargeable ZIBs based on delta-type manganese oxide (δ-MnO2 ) intercalation electrode. The behavior of the zinc electrode on stripping and deposition in ChCl/urea electrolyte was examined. Besides, the charge storage and charge-transfer characteristics of the battery was studied. The results showed that there was no sign of dendrite formation on the zinc electrode during long-term cycling. Consequently, the fabricated battery exhibited good electrochemical performance with the maximum specific capacity of 170 mAh/g and good cyclability. In addition, the system showed reversible plating/stripping of zinc (Zn) without dendrite formation and no passivation layer on the zinc electrode. Hence, the results confirmed the reversible intercalation of Zn from the deep eutectic solvent ChCl/urea into the δ-MnO2 electrode. Overall, the proposed electrolyte shows good promise for Zn/δ-MnO2 battery system.