Evaluation of MIEC Ce0.8Y0.1Mn0.1O2-δ Anode in Electrolyte-Supported SOFC. Issue 11 (1st January 2016)

• Record Type: Journal Article
• Authors: Handal, Hala T.; Addo, Paul; Buyukaksoy, Aligul; Birss, Viola; Thangadurai, Venkataraman
• Is Part Of: Journal of the Electrochemical Society. Volume 163:Issue 11(2016)
• Page Start: F3091
• Page End: F3098
• Publication Date: 2016-01-01
• Subjects: Doped ceria anodes -- Electrolyte-supported SOFC -- SOFC performance -- Sulfur tolerance; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0121611jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : In this study, the electrochemical performance of a single phase, mixed ion and electron conducting (MIEC) Ce0.8 Y0.1 Mn0.1 O2-δ (10CYMO) anode was evaluated using symmetrical half-cell and full-cell configurations under humidified H2, 10 ppm H2 S/H2, and CH4 . An yttria-stabilized zirconia (YSZ) electrolyte support layer was used in this work, as ac impedance spectroscopy revealed that the 10CYMO/YSZ/10CYMO cell gave the lowest area specific polarization resistance (ASR) of 0.23 Ωcm 2 at 800°C in wet H2, compared to La0.8 Sr0.2 Ga0.8 Mg0.2 O3-δ (LSGM) and Zr0.89 Sc0.1 Ce0.01 O2-δ (ScSZ). Exposure of the 10CYMO anodes to 10 ppm H2 S/H2, either in a half-cell or full cell configuration, showed slight enhancement on the electrochemical performance, which was explained using a concept describing the sulfur and ceria interaction. The performance of a 10CYMO/YSZ/La0.8 Sr0.2 MnO3-δ _ YSZ full cell was evaluated under 90%H2 -N2 /3%H2 O, giving a power density of 75 mW/cm 2 at 800°C and is better than seen for other fluorite-based anodes reported in the literature.