Olivine-LiNiPO4 Thin Films: Chemical Compatibility with Liquid Electrolyte and Interface Stability at High Potential. Issue 4 (1st January 2018)

• Record Type: Journal Article
• Authors: Cherkashinin, Gennady; Eilhardt, Robert; Lebedev, Mikhail V.; Nappini, Silvia; Magnano, Elena; Jaegermann, Wolfram
• Is Part Of: Journal of the Electrochemical Society. Volume 165:Issue 4(2018)
• Page Start: H3143
• Page End: H3147
• Publication Date: 2018-01-01
• Subjects: LiNiPO4 -- solid electrolyte interface -- SPES and soft-XANES; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0211804jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : The chemical compatibility between carbon free olivine-LiNiPO4 thin films used as cathode material and LiPF6 /DMC/FEC/0.2%-TMB liquid electrolyte was studied by soft-photoelectron spectroscopy, Ni L- and O K- XANES combined with electrochemical experiments. The stability of the electrolyte-electrode interface at a high charging potential strongly depends on the temperature of LiNiPO4 preparation. For the films grown at 740°C, the chemical composition of the interface is not changed even at a charging potential of 5.2 V, whereas the electrolyte-electrode interface of LiNiPO4 grown at lower temperatures (675°C) decomposes at 5.1 V, involving the cathode material in the chemical reaction.