Acrylic Acid-Based Copolymers as Functional Binder for Silicon/Graphite Composite Electrode in Lithium-Ion Batteries. Issue 12 (1st January 2015)

• Record Type: Journal Article
• Authors: Aoki, Shoko; Han, Zhen-Ji; Yamagiwa, Kiyofumi; Yabuuchi, Naoaki; Murase, Masahiro; Okamoto, Kuniaki; Kiyosu, Takahiro; Satoh, Michihiko; Komaba, Shinichi
• Is Part Of: Journal of the Electrochemical Society. Volume 162:Issue 12(2015)
• Page Start: A2245
• Page End: A2249
• Publication Date: 2015-01-01
• Subjects: binder -- lithium-ion battery -- silicon; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0171512jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : Acrylic acid-based copolymers are synthesized by polymerization of acrylic acid with a small portion of crosslinker, diallyl ethers. The obtained copolymers are soluble in water, and viscosity of their aqueous solution incrementally varies with increase in the amount of crosslinker and neutralization degree of -COOH groups with NaOH. The copolymers are examined as binders for silicon/graphite composite electrodes for lithium-ion batteries. Reversibility and lithiation capacity of the composite are highly improved by the selection of copolymers, which is due to better homogeneity and mechanical durability of the composite electrodes.