Nitrogen and Sulfur Dual-Doped Carbon Microtubes with Enhanced Performances for Oxygen Reduction Reaction. Issue 5 (1st January 2016)

• Record Type: Journal Article
• Authors: Deng, Libo; Fang, Haoming; Zhang, Peixin; Abdelkader, Amr; Ren, Xiangzhong; Li, Yongliang; Xie, Ning
• Is Part Of: Journal of the Electrochemical Society. Volume 163:Issue 5(2016)
• Page Start: H343
• Page End: H349
• Publication Date: 2016-01-01
• Subjects: Biomass-carbon -- Dual-doping -- Electrocatalyst -- Graphitization; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.1131605jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : Porous carbon microtubes were prepared by pyrolysing an inexpensive and abundant natural fungus at a high temperature, followed by activation and doping with nitrogen (N) and sulfur (S) elements at a lower temperature. The performance of the porous carbon as electrocatalysts for oxygen reduction reaction (ORR) was systematically investigated. The pristine carbon without doping shows a high electrocatalytic activity, which is strongly dependent on the degree of graphitization. By N- and S- dual-doping, the catalytic performance is further enhanced, exhibiting a four-electron oxygen reduction pathway, which is attributed to the redistribution of spin and charge densities. These results suggest that obtaining graphitic porous carbon from natural precursors combined with heteroatom-doping, provide an effective method of producing high performance carbon materials which might be suitable for various electrochemical energy applications.