Application of Cross-Linked Polyborosiloxanes and Organically Modified Boron Silicate Binders in Silicon-Containing Anodes for Lithium-Ion Batteries. Issue 5 (1st January 2018)

• Record Type: Journal Article
• Authors: Shariaty, Darius A.; Qian, Dali; Cheng, Yang-Tse; Odom, Susan A.
• Is Part Of: Journal of the Electrochemical Society. Volume 165:Issue 5(2018)
• Page Start: A731
• Page End: A735
• Publication Date: 2018-01-01
• Subjects: organically modified boron silicate -- polyborosiloxane -- silicon; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0801803jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : To determine the effect of cross-linking in polymer binders on gravimetric capacity and retention in charge/discharge cycling of lithium-ion batteries containing silicon anodes, polymers with a varied chemiophysical characters have been studied as electrode binders. Here we report the utilization of cross-linked polyborosiloxanes and a boron-modified organosilicate as binders for nanoparticulate silicon-containing anodes for lithium-ion batteries. We show that highly cross-linked binders enable a large degree of capacity to be accessed and that capacity retention is greater when the electrodes are cycled in half cells. More extensive analysis of the boron-modified organosilicate is further explored.