Flexible Three-Dimensional Heterostructured ZnO-Co3O4 on Carbon Cloth as Free-Standing Anode with Outstanding Li/Na Storage Performance. Issue 16 (1st January 2018)

• Record Type: Journal Article
• Authors: Chen, Huanhui; Deng, Libo; Luo, Shan; Ren, Xiangzhong; Li, Yongliang; Sun, Lingna; Zhang, Peixin; Chen, Guoqiang; Gao, Yuan
• Is Part Of: Journal of the Electrochemical Society. Volume 165:Issue 16(2018)
• Page Start: A3932
• Page End: A3942
• Publication Date: 2018-01-01
• Subjects: Batteries -- Co3O4 -- flexible battery -- heterostructure; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0721816jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : Herein, a facile and binder-free method was developed to prepare a flexible electrode for dual battery applications, which was achieved by fabricating nanosheets of ZnO-Co3 O4 heterostructures attached on the surface of highly conductive carbon cloth (CC). Remarkably, for Li-ion batteries, the combined effects of two dimensional (2D) heterostructural and three dimensional (3D) carbon fiber substrate offered an excellent reversible capacity rate of approximately 1785 mAh g −1 at a current density of 200 mA g −1 . Even at a charge-discharge rate of 2000 mA g −1, the ZnO-Co3 O4 @CC composite exhibited a reversible capacity of 491 mAh g −1 after 400 cycles. For sodium-ion batteries, the composite exhibited a reversible specific capacity of 684 mAh g −1 at a current density of 200 mA g −1 and a capacity of 265 mAh g −1 after 500 cycles at a current density of 1000 mA g −1 . Flexible half-cells were also constructed, which exhibited high flexibility and excellent electrochemical performance. The excellent performance is mainly due to the in situ growth of ZnO-Co3 O4 nanosheets on the CC, which provided a large contact area between the active material and the flexible and conductive substrate, ultimately facilitating rapid electron transport and preventing the aggregation of large surface area nanosheets.