High-Energy Nickel-Rich Layered Cathode Stabilized by Ionic Liquid Electrolyte. Issue 6 (1st January 2019)

• Record Type: Journal Article
• Authors: Heist, Ashley; Hafner, Simon; Lee, Se-Hee
• Is Part Of: Journal of the Electrochemical Society. Volume 166:Issue 6(2019)
• Page Start: A873
• Page End: A879
• Publication Date: 2019-01-01
• Subjects: Batteries -- Batteries - Lithium -- Ionic Liquid Electrolyte -- lithium-ion battery -- Nickel-Rich Layered Cathode; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0071906jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : In order to meet the critical energy-storage challenges of the future, a next-generation lithium-ion battery will need to achieve a higher energy density and longer cycle life. While increasing the nickel content in layered LiMO2 (M = Ni, Mn, Co) significantly improves the capacity of the material, nickel-rich cathodes cycled in conventional organic electrolytes commonly suffer from crystallographic phase transformation and the growth of a resistive interfacial layer, both of which result in voltage fade and capacity degradation during cycling. However, pairing a nickel-rich cathode with an appropriate ionic liquid (IL) electrolyte enables exceptional cycling stability and energy retention. This work demonstrates how a pyrrolidinium-based IL electrolyte not only allows for cycling to higher voltages but shows a 95% energy retention and average discharge capacity of 189 mAh g −1 over 150 cycles between 3 and 4.5 V vs. Li/Li + with a nickel-rich layered cathode. Based on electrochemical and crystallographic analyses, the exceptional performance of the cells cycled in IL is attributed to the stability of the electrode-electrolyte interfacial layer formed by the IL which protects the active material and suppresses the structural degradation commonly observed in nickel-rich cathodes.