Communication—Electrochemical Reduction of Nitrogen to Ammonia in 2-Propanol under Ambient Temperature and Pressure. Issue 7 (1st January 2016)

• Record Type: Journal Article
• Authors: Kim, Kwiyong; Lee, Nara; Yoo, Chung-Yul; Kim, Jong-Nam; Yoon, Hyung Chul; Han, Jong-In
• Is Part Of: Journal of the Electrochemical Society. Volume 163:Issue 7(2016)
• Page Start: F610
• Page End: F612
• Publication Date: 2016-01-01
• Subjects: 2-propanol -- Ammonia -- Electrochemical reduction -- Nitrogen; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0231607jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : Selection of an appropriate electrolyte medium is essential for successful NH3 electro-synthesis at low temperature and pressure. In this study, 2-propanol was employed as an electrolyte medium and its effectiveness in the electro-reduction of N2 to NH3 under ambient conditions was evaluated. NH3 synthesis and faradaic efficiency using a mixture of 2-propanol/water (9:1, v/v) surpassed those when electrosynthesis was carried out using solely water. The concentration of H2 SO4 and the applied current density influenced NH3 synthesis in this 2-propanol-based system, and the optimal conditions led to maximized N2 reduction, indicating that the competing and electron-losing reaction of H2 evolution was relatively well suppressed.