Bio-sourced monomers and cationic photopolymerization–The green combination towards eco-friendly and non-toxic materials. (April 2022)

• Record Type: Journal Article
• Authors: Pierau, Lucie; Elian, Christine; Akimoto, Jun; Ito, Yoshihiro; Caillol, Sylvain; Versace, Davy-Louis
• Is Part Of: Progress in polymer science. Volume 127(2022)
• Publication Date: 2022-04
• Subjects: Epoxy monomers -- Bio-based polymers -- Renewable resources -- Photochemistry -- Cationic photopolymerization; 33DDS 3, 3'-diaminodiphenylsulphone -- 3HF 3-hydroxyflavone -- AESO Acrylated epoxidized soybean oil -- BADGE Bisphenol A diglycidyl ether -- BAPO Bis-acylphosphine -- bFdE Bis-furan diepoxide -- Bis-GMA Bisphenol A glycidyl dimethacrylate -- BPA Bisphenol A -- BPB Bisphenol B -- BPM Bisphenol M -- BPS Bisphenol S -- CHO Cyclohexene oxide -- CMD1-4 Curcuminoid derivatives -- CNSL Cashew nutshell liquid -- CP Cationic (photo)polymerization -- CQ Camphorquinone -- DB1 Disperse blue 1 -- DB3 Disperse blue 3 -- DDM 4, 4'-diaminodiphenyl methane -- DETA Diethylenetriamine -- DGEBA Diglycidyl ether bisphenol A -- DGEVA Diglycidylether of vanillyl alcohol -- DGFDC Diglycidyl furan-2, 5-dicarboxylate -- DHAQ Dihydroxyanthraquinone -- DMF Dimethylformamide -- DMPA 2, 2-dimethoxy-2-phenylacetophenone -- DSC Differential scanning calorimetry -- DSO Dihydroxy soybean oil -- DVE-3 Tri(ethylene glycol) divinyl ether -- ECD Epoxidized cardanol derivatives -- ECH Epichlorohydrin -- ECHA European Chemicals Agency -- ECLO Epoxidized cyclohexene linseed oil -- ECO Epoxidized castor oil -- EGE Eugenol glycidyl ether -- ELNR Epoxidized liquid natural rubber -- ELO Epoxidized linseed oil -- EMX Epoxidized fatty acid methyl esters -- ENLO Epoxynorbornane linseed oil -- EPOX (3, 4-epoxycyclohexane)methyl 3, 4-epoxycyclohexylcarboxylate -- EPR Electronic paramagnetic resonance -- ESO Epoxidized soybean oil -- EVO Epoxidized vegetable oil -- FCA 2-furan carboxylic acid -- FDCA 2, 5-furan dicarboxylic acid -- FdE Furan diepoxide -- FDM 2, 5-furan dimethanol -- FM 2-furan methanol -- FmE Furan monoepoxide -- FRP Free radical (photo)polymerization -- FRPCP Free radical-promoted cationic polymerization -- GEC Glycidyl ether of catechin -- HEMA 2-hydroxyethylmethacrylate -- HMDA Hexamethylenediamine -- HNQ Hydroxy-1, 4-naphthoquinone -- HNQA Allylated hydroxy-1, 4-naphthoquinone -- HNQE Epoxidized hydroxy-1, 4-naphthoquinone -- HSA (R)-12-hydroxystearic acid -- IBVE Isobutyl vinyl ether -- INA Ice nucleation active -- Iod Iodonium salt -- IPDA Isophorone diamine -- LDO Limonene dioxide -- LED Light-emitting diode -- Lim Limonene-1, 2-epoxide -- m-CPBA Meta-chloroperoxybenzoic acid -- MMA Methyl methacrylate -- MN Micronuclei -- MXDA m-xylylenediamine -- NVK N-vinylcarbazole -- OBN Oil blue N -- OPC Organic photoredox compound -- P Purpurin -- PA Tri-allyl purpurin -- PAG Photoacid generator -- PET Poly(ethylene) terephthalate -- PHA Polyhydroxyalkanoate -- PHF Penta-hydroxy flavone -- PHTE Phloroglucinol trisepoxy -- PI Photoinitiator -- PIS Photoinitiating system -- PLP Pulsed laser polymerization -- PmA Mono-allyl purpurin -- POM Polyoxometalate -- PS Photosensitizer -- PSA Pressure-sensitive adhesives -- PVC Poly(vinyl) chloride -- QA Di-allyl quinizarin -- QE Di-epoxy quinizarin -- QZ Quinizarin -- RGDE Resorcinol diglycidyl ether -- RNS Reactive nitrogen species -- ROP Ring-opening polymerization -- ROS Reactive oxygen species -- SOC Spiroorthocarbonate -- TBBPA Tetrabromobisphenol A -- TEEP Tri(epoxidized-eugenyl) phosphate -- TEGDMA Tri(ethylene glycol) dimethacrylate -- TEOS Tetraethylorthosilicate -- TEP Tri(eugenyl) phosphate -- Tg Glass transition temperature -- THAQ Tri/tetra-hydroxyanthraquinone -- TPO 2, 4, 6-trimethylbenzoyldiphenyl phosphine oxide -- UDMA Urethane dimethacrylate -- γ-TO γ-terpinene oxide; Polymers -- Periodicals; Polymerization -- Periodicals; Polymers -- Industrial applications -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.progpolymsci.2022.101517
• Languages: English
• ISSNs: 0079-6700

Abstract

Abstract: Cationic photopolymerization is amongst the greenest processes used to obtain polymers since light is abundant, inexpensive and allows for rapid and waste-less curing at room temperature. Moreover, in the current search for the reduction of the environmental impacts of polymers, the use of biobased monomers is one of the most crucial stakes. At the crossroads of these domains, biobased monomers photopolymerization offers the best of both. Hence, this review aims at underlying the increasing importance of cationic photopolymerization in combination with bio-based photopolymerizable monomers, and describes the numerous reactive species derived from bioresources that can lead to innovative materials through cationic photopolymerization reactions. This review intends to be a guide to orientate academic teams and industries involved in reducing both environmental impacts and toxicity towards the synthesis of environmentally safe materials. The recent advances on the photochemical systems used, the toxicity of the cationic photoinitiating systems, the reactivity of the new epoxy bio-sourced monomers, their thermomechanical properties as well as the applications of the targeted materials will be described. Graphical abstract: Image, graphical abstract