Structurally Engineered Anisotropic Cobalt‐Based Nanostructures for Efficient Chlorine and Oxygen Evolution. Issue 21 (28th June 2022)

• Record Type: Journal Article
• Authors: Rana, Supriya; Yadav, Krishna K.; Sunaina, ; Mehta, Surinder K.; Jha, Menaka
• Is Part Of: Advanced materials interfaces. Volume 9:Issue 21(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-06-28
• Subjects: Cl 2 evolution -- electrochemistry -- hcp‐Co -- O 2 evolution -- self‐assembly; Materials science -- Periodicals; 620.11
• DOI: 10.1002/admi.202200740
• Languages: English
• ISSNs: 2196-7350

Abstract

Abstract: Electrochemical Cl2 generation using inexpensive electrocatalysis has drawn tremendous scientific attention to meet the future demand for chlorine. The present work deals with the design of the chemical process to synthesize anisotropically aligned metallic hcp‐cobalt nanoparticles. The as‐obtained hcp‐cobalt rods are utilized for the generation of O2 and Cl2 via an electrochemical process. Controlling the thermodynamic parameters during the thermal decomposition of cobalt oxalate rods leads to the formation of aligned nanoparticles. Detailed microscopic investigation shows that the slow heating rate favors the anisotropic growth of nanoparticles, and the fast‐heating rate leads to the formation of agglomerated nanoparticles. Anisotropically aligned hcp‐Co rods show an overpotential of 240 and 30 mV for O2 and Cl2 evolution, respectively. These findings elaborate that aligned particles (rod‐like structures) show promising electrocatalysts with better efficiency for O2 and Cl2 generation. Further, wastewater treatment is done by using in situ generated chlorine and 99% degradation efficiency is observed for textile effluents (methyl orange). Abstract : The anisotropically aligned metallic hcp‐cobalt nanoparticle has been synthesized and utilized for electrochemical O2 and Cl2 generation. The slower heating rate favors the formation of aligned hcp‐Co nanorods and shows 240 and 30 mV overpotential for O2 and Cl2 evolution, respectively. Further, in situ generated chlorine is used for textile effluents removal and 99% degradation efficiency has been observed.