Asymmetric cyclopropanation of electron-rich alkenes by the racemic diene rhodium catalyst: the chiral poisoning approach. Issue 47 (20th May 2022)
- Record Type:
- Journal Article
- Title:
- Asymmetric cyclopropanation of electron-rich alkenes by the racemic diene rhodium catalyst: the chiral poisoning approach. Issue 47 (20th May 2022)
- Main Title:
- Asymmetric cyclopropanation of electron-rich alkenes by the racemic diene rhodium catalyst: the chiral poisoning approach
- Authors:
- Trifonova, Evgeniya A.
Ankudinov, Nikita M.
Chusov, Denis A.
Nelyubina, Yulia V.
Perekalin, Dmitry S. - Abstract:
- Abstract : A chiral auxiliary ligand can selectively poison one enantiomer of the racemic diene Rh(i ) complex providing an opportunity for asymmetric cyclopropanation. Abstract : Asymmetric cyclopropanation of alkenes by aryldiazoacetates was achieved using the readily-available racemic (diene)rhodium complex in combination with the chiral oxazoline-phenol ligand, which acts as the chiral poison and selectively inhibits one of the enantiomers of the catalyst. This approach eliminates a common problematic step of the synthesis of chiral catalysts.
- Is Part Of:
- Chemical communications. Volume 58:Issue 47(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 47(2022)
- Issue Display:
- Volume 58, Issue 47 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 47
- Issue Sort Value:
- 2022-0058-0047-0000
- Page Start:
- 6709
- Page End:
- 6712
- Publication Date:
- 2022-05-20
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc01648f ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 22686.xml