Recent progress on thermally conductive and electrical insulating rubber composites: Design, processing and applications. (December 2020)

• Record Type: Journal Article
• Authors: Niu, Hongyu; Ren, Yanjuan; Guo, Haichang; Małycha, Katarzyna; Orzechowski, Kazimierz; Bai, Shu-Lin
• Is Part Of: Composites communications. Volume 22(2020)
• Publication Date: 2020-12
• Subjects: Thermally conductive composites -- Electrical insulation -- Rubber -- Ceramic fillers -- Filler orientation -- 3D interconnected network
• DOI: 10.1016/j.coco.2020.100430
• Languages: English
• ISSNs: 2452-2139

Abstract

Abstract: Thermal management plays a vital role in the performance, lifespan and stability of electronic devices, especially with the new emergence of 5G network. High thermal conductivity (TC) and electrical insulating rubber composites are widely used as thermal interface materials owing to their good performance. Herein, fundamental design principles of rubber composites with high TC and excellent electrical insulation are emphasized. Properties and the latest research progress of thermally conductive ceramic fillers (BN, Al3 O2, AlN, etc.) are introduced at length. Besides, factors that influence thermal interfacial resistance, including geometry, preparation methods and interfacial compatibility, are overviewed as well. More attention is paid to strategies for 2D filler orientation and 3D structure engineering of composites which are expected to achieve higher TC in horizontal and/or vertical direction. Finally, emerging applications of thermally conductive and insulating rubber composites in electronic industry and new-energy automobile are demonstrated. Highlights: Recent progress on thermally conductive and electrical insulating rubber composites is summarized systematically. Fundamental properties and new progress of ceramic fillers, BN, AlN, Al2 O3, are introduced. Strategies for filler orientation and 3D network formation are emphasized. Emerging applications of thermally conductive and electrical insulating rubber composites are demonstrated.