Catalytically Active CoSe2 Supported on Nitrogen‐Doped Three Dimensional Porous Carbon as a Cathode for Highly Stable Lithium‐Sulfur Battery. Issue 7 (23rd February 2022)

• Record Type: Journal Article
• Authors: Zhang, Fenglong; Wang, Hui; Ji, Shan; Linkov, Vladimir; Wang, Xuyun; Wang, Rongfang
• Is Part Of: Chemphyschem. Volume 23:Issue 7(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-02-23
• Subjects: CoSe2 -- N-doped carbon -- cathode -- stability -- lithium-sulfur battery; Chemistry, Physical and theoretical -- Periodicals; 541.05
• DOI: 10.1002/cphc.202100811
• Languages: English
• ISSNs: 1439-4235

Abstract

Abstract: Lithium‐sulfur batteries are promising secondary energy storage devices that are mainly limited by its unsatisfactory cyclability owing to inefficient reversible conversion of sulfur and lithium sulfide on the cathode during the discharge/charging process. In this study, nitrogen‐doped three‐dimensional porous carbon material loaded with CoSe2 nanoparticles (CoSe2 ‐PNC) is developed as a cathode for lithium‐sulfur battery. A combination of CoSe2 and nitrogen‐doped porous carbon can efficiently improve the cathode activity and its conductivity, resulting in enhanced redox kinetics of the charge/discharge process. The obtained electrode exhibits a high discharge specific capacity of 1139.6 mAh g −1 at a current density of 0.2 C. After 100 cycles, its capacity remained at 865.7 mAh g −1 thus corresponding to a capacity retention of 75.97 %. In a long‐term cycling test, discharge specific capacity of 546.7 mAh g −1 was observed after 300 cycles performed at a current density of 1 C. Abstract : Nitrogen doped porous carbon loaded with CoSe2 nanoparticles is evaluated as a cathode material for lithium‐sulfur batteries. The three dimensional material exhibits a high discharge specific capacity of 1139.6 mAh g −1 at 0.2 C with a retention capacity of 75.97 % after 100 cycles.