A Comparison of Edge‐plane and Basal‐plane Pyrolytic Graphite Electrodes towards Sensitive Determination of the Fungicide Mandipropamid. Issue 4 (18th November 2020)

• Record Type: Journal Article
• Authors: Festinger, Natalia; Lemiesz, Adrianna; Skowron, Ewelina; Smarzewska, Sylwia; Ciesielski, Witold
• Is Part Of: Electroanalysis. Volume 33:Issue 4(2021)
• Page Start: 854
• Page End: 863
• Publication Date: 2020-11-18
• Subjects: Electrochemistry -- Highly ordered pyrolytic graphite -- Mandipropamid -- Pyrolytic graphite electrode -- Voltammetry; Electrochemical analysis -- Periodicals; Chemistry, Analytical -- Periodicals; Electrochemistry -- Periodicals; 543.4
• DOI: 10.1002/elan.202060387
• Languages: English
• ISSNs: 1040-0397

Abstract

Abstract: A sensitive square‐wave voltammetry (SWV) method based on basal‐plane pyrolytic graphite electrode (BPPGE) and edge‐plane pyrolytic graphite electrode (EPPGE) was developed to determine the concentration of the pesticide mandipropamid (MAN) in spiked river water and grape juice samples. Under optimal experimental conditions, the SWV response of EPPGE and BPPGE was linear over the concentration ranges of 0.7 to 9.0 μmol L −1 and 0.5 to 10.0 μmol L −1, respectively. The method was successfully used to determine MAN in spiked samples with good recovery. Cyclic voltammetry (CV) was conducted to understand the mechanism underlying the electrode process of MAN. Abstract :