The Solubility of Tugarinovite (MoO2) in H2O at Elevated Temperatures and Pressures. (18th December 2017)

• Record Type: Journal Article
• Authors: Saha, Pritam; Anderson, Alan J.; Lee, Thomas; Klemm, Matthias
• Other Names: Stefansson Andri Academic Editor.
• Is Part Of: Geofluids. Volume 2017(2017)
• Publication Date: 2017-12-18
• Subjects: Hydrogeology -- Periodicals; Sedimentary basins -- Periodicals; Fluids -- Migration -- Periodicals; Groundwater flow -- Periodicals; Geothermal resources -- Periodicals; Fluid dynamics -- Periodicals; Earth -- Crust -- Periodicals; 551.49
• DOI: 10.1155/2017/5459639
• Languages: English
• ISSNs: 1468-8115

Abstract

Abstract : The solubility of tugarinovite (MoO2 ) in pure water was investigated at temperatures between 400 and 800°C and at pressures ranging between 95 and 480 MPa by using in situ synchrotron X-ray fluorescence (SXRF) to separately analyze high temperature aqueous solutions in a hydrothermal diamond anvil cell (HDAC). The concentration of molybdenum in the fluid at 400 and 500°C was below detection; however, at temperatures between 600 and 800°C, the solubility of tugarinovite increased with increasing temperature by two orders of magnitude. The molybdenum concentration at 600°C and 800°C is 44 ppm and 658 ppm, respectively. The results complement the data of Kudrin (1985) and provide the first measurement of MoO2 solubility at pressure and temperature conditions comparable to intrusion-related Mo deposit formation. The data are also relevant to the study of water chemistry and corrosion product transport in supercritical-water-cooled reactors, where Mo-bearing steel alloys interact with aqueous solutions at temperatures greater than 600°C. The application of in situ SXRF to solubility measurements of sparingly soluble minerals is recommended because it circumvents analytical uncertainties inherent in determinations obtained by quenching and weight loss measurements.