A Sustainable Self‐Induced Solution Seeding Approach for Multipurpose BiFeO3 Active Layers in Flexible Electronic Devices. (10th April 2022)

• Record Type: Journal Article
• Authors: Barrios, Óscar; Jiménez, Ricardo; Ricote, Jesús; Tartaj, Pedro; Calzada, María Lourdes; Bretos, Íñigo
• Is Part Of: Advanced functional materials. Volume 32:Number 27(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-04-10
• Subjects: electronic devices -- flexible thin films -- multifunctional oxides -- seeding effect -- solution processing; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.202112944
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: The direct integration of crystalline oxide layers into flexible electronic systems requires the development of relatively simple, low‐temperature processing routes. Seeding represents a powerful strategy to reach this objective by the generation of preferential sites for the nucleation of crystalline phases with a reduced energy barrier. Here, a novel approach is reported where nanoseeds are generated in situ from a precursor solution using a solvent‐engineering strategy (solvent‐antisolvent). The controlled addition of an antisolvent (1, 3‐propanediol) to a solution of metal salts (Bi/Fe) dissolved in acetic acid results in the formation of nanocrystals (seeds) by supersaturation. The presence of such nanoseeds is also confirmed in the deposited layers, improving significantly the crystallinity of the respective BiFeO3 thin films as complementary, deduced by piezoresponse force microscopy. Using this low‐temperature strategy, crystalline films are directly grown on flexible polymeric substrates at only 350 °C showing a remanent polarization of 10.5 µC cm −2 and a clear photovoltaic effect (11.7 µW cm −2 ) of interest in computer memories and energy harvesters. The flexibility of the BiFeO3 thin films may enlarge the number of applications of this multifunctional, lead‐free material in next‐generation digital and sustainable electronic devices based on a facile, low‐cost fabrication method with reduced energy consumption. Abstract : The development of a low‐temperature strategy based on a solvent‐engineering approach makes possible the crystallization of BiFeO3 thin films at 350 °C on flexible polymeric substrates. The films show a remanent polarization of 10.5 µC cm −2 and power output under illumination of 11.7 µW cm −2 that support their application in next‐generation devices such as flexible computer memories and energy harvesters.