The Sulfinylsulfonation of alkynes for β‐Sulfinyl alkenylsulfone. Issue 14 (18th May 2022)

• Record Type: Journal Article
• Authors: Zhang, Zhansong; Song, Qingmin; Feng, Chengjie; Wang, Zikun; Zhao, Wanjun; Ning, Yongquan; Wu, Yong
• Is Part Of: Chemistry, an Asian journal. Volume 17:Issue 14(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-05-18
• Subjects: Alkynes -- Sodium sulfinate -- Sulfinylsulfonation Sulfones -- β-Sulfinyl alkenylsulfone; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.202200299
• Languages: English
• ISSNs: 1861-4728

Abstract

Abstract: Here we report the sulfinylsulfonation of alkynes to afford β‐sulfinyl alkenylsulfone products with a broad substrate scope, excellent functional group compatibility, and high yield. Moreover, the sulfinylsulfonation reaction of enyne can also be realized for constructing functionalized carbo‐ and heterocycles through a radical cascade cyclization process. Abstract : Sulfinylsulfonation of alkynes to afford β‐sulfinyl alkenylsulfone products with a broad substrate scope, excellent functional group compatibility, and high yield has been reported. Moreover, sulfinylsulfonation reaction of enyne can also be realized for constructing functionalized carbo‐ and heterocycles through a radical cascade cyclization process.