Experimental and computational approaches to study the chlorination mechanism of pentlandite with ammonium chloride. Issue 30 (1st July 2022)

• Record Type: Journal Article
• Authors: Xiong, Xiaolu; Li, Guangshi; Pang, Zhongya; Chen, Sha; Zou, Xingli; Xu, Qian; Cheng, Hongwei; Li, Shenggang; Zhu, Kai; Lu, Xionggang
• Is Part Of: RSC advances. Volume 12:Issue 30(2022)
• Page Start: 19232
• Page End: 19239
• Publication Date: 2022-07-01
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d2ra03488c
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : The chlorination mechanism of pentlandite with NH4 Cl has been proposed. The chlorination of pentlandite can be achieved by two pathways, where O2 plays a crucial role in promoting the chlorination process. Abstract : Pentlandite (Fe4.5 Ni4.5 S8 ) is the primary source for the metallurgical production of nickel worldwide, however it usually coexists with copper sulfide in nature. To develop an efficient and green process for the separation and extraction of valuable metals from the nickel sulfide concentrate, herein we conducted experimental studies and density functional theory (DFT) calculations to elucidate the chlorination mechanism of pentlandite using ammonium chloride (NH4 Cl). First, low-temperature chlorination roasting experiments with NH4 Cl were performed in which pentlandite was successfully converted into the corresponding metal chlorides (FeCl2 and NiCl2 ). Then, the chlorination product was analyzed via energy dispersive spectrometry to reveal the elemental distribution at the cross-section. Results reveal that Fe atoms in pentlandite underwent preferential chlorination to form a chloride layer, whereas Ni atoms remained at the center of the grain. Furthermore, density functional theory calculations were performed to investigate the chlorination mechanism of pentlandite by exploring two possible pathways, involving the adsorption of oxygen (O2 ), ammonium chloride (NH4 Cl) and chlorine (Cl2 ) on both the (001) and (010) surfaces of pentlandite. Considering that the chlorination of pentlandite was achieved in air atmosphere, we first consider the direct chlorination of pentlandite by NH4 Cl in the presence of oxygen. Dissociative oxygen adsorption was found to promote the chlorination process by providing oxygen sites for the dissociation of HCl, which is decomposed from NH4 Cl, eventually leading to the formation of H2 O and FeCl2 species. Alternatively, the reaction between pentlandite and Cl2 was proved to be feasible thermodynamically.