Metal–Organic Framework Derived Bimetallic Materials for Electrochemical Energy Storage. (3rd December 2020)

• Record Type: Journal Article
• Authors: Sanati, Soheila; Abazari, Reza; Albero, Josep; Morsali, Ali; García, Hermenegildo; Liang, Zibin; Zou, Ruqiang
• Is Part Of: Angewandte Chemie. Volume 133:Number 20(2021)
• Page Start: 11148
• Page End: 11167
• Publication Date: 2020-12-03
• Subjects: bimetallic materials -- electrode materials -- energy storage -- metal–organic frameworks -- supercapacitors; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202010093
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Supercapacitors (SCs), showing excellent power density, long service life, and high reversibility, have received great attention because of the increasing demand for energy storage devices. To further improve their performance, it is essential to develop advanced electrode materials. One group of materials, porous crystalline solids referred to as metal–organic frameworks (MOFs), have proved to be excellent templates for synthesizing functional materials to be employed in the preparation of electrodes for SCs. In comparison to monometallic MOFs, bimetallic MOFs and their derivatives offer a number of advantages, including tunable electrochemical activity, high charge capacity, and improved electrical conductivity. This review focuses on the use of MOF‐derived bimetallic materials in SCs, the origin of the improved performance, and the latest developments in the field. Furthermore, the challenges and perspectives in this research area are discussed. Abstract : Bimetallic metal–organic frameworks (MOFs) have been applied as sacrificial templates or precursors in the preparation of derivatives that can be used in supercapacitors. Bimetallic MOFs and their derivatives can offer the advantages of improved electrochemical activity, convenient redox reactions, and high electrical conductivity, and are excellent candidates as advanced electrode materials.